The image below shows a row of solder joints on a large BGA near the center of the row.

The corner balls on the BGA were elongated into an “hour glass” shape due to the warpage of the package (e.g. image below). 

The chart below shows the solder joint height versus the distance from the corner ball for three different assemblies (Ax, BX, & CX).

The amount of warpage in BGA assembly is driven by a number a factors including the BGA design, the board design, and the reflow process parameters (e.g. top versus bottom-side temperature and cool down rate).  In the present case, it appeared that the BGA design (i.e. CTE constrained by large die) was the primary factor.

This is the solder-side of a PCBA that failed shorted.  The cause of the short was determined to be electrochemical migration (ECM), but there were secondary effects as shown in the next image.

These are vapor deposited copper & tin crystals that most likely formed as a result of the failure where vaporized copper & tin condensed as these feathery structures.

The EDS spectrum suggest the composition of the crystals includes copper & tin.

Pb-dendrites on the edge of a die caused by electro-chemical corrosion.

This is BSE SEM image of a microsection of a flex circuit showing two internal copper conductor layers.

This is an area where the copper conductor is corroded.  The corrosion initially attacks the grain boundaries.

This image shows that the corrosion completely consumed the copper layer at this location(top-right segment).

This is a through-hole solder joint where the internal copper conductors are almost completely gone due to corrosion as well as the nickel surface lands.

This is a higher magnification image that shows the missing material more clearly.

This is an elemental map that also shows the missing copper layers and nickel lands more clearly.

Some tips to avoid this type of corrosion include …

1.  chose compatible materials (adhesives and other polymers can contain chlorides, sulfur, etc. … add moisture and voltage bias and corrosion  can accelerate dramatically)
2.  clean thoroughly &  DRY at each appropriate process step (this includes bare flex fabrication and assembly processes)
3.  thermal damage can create paths for ionic contamination and moisture to migrate into the internal conductors, so minimize thermal exposure

This post discusses the differences between optical images and SEM images.

This is an optical image of a flea.

This is a 20 kV secondary electron (SE) image of the same flea.

The optical image has good color contrast, which is often complimentary to SEM imaging.  The SEM image has no color (gray scale), but shows far more surface detail and depth of focus compared with the optical image.

This is a 20 kV backscattered electron (BSE) image of the flea.

The backscattered electron signal is proportional to the average atomic number of the material being imaged, so in this case the carbon tape background and the flea (mostly carbon) are of similar contrast.

       This is a 2 kV SE image of the flea. 

At lower accelerating voltage more of the fines surface details are apparent, but there is less signal and lower contrast.

Higher magnification 2 kV SE image.

The advantage of SEM imaging is the high magnification with resolution, which allows for examination of small (often sub-micron) features that would not be possible using optical wavelengths.

FTIR can identify unknown plastic materials by comparison with known materials (i.e. from a spectral library).

A client provided four aluminum electrolytic capacitors to SEM Lab, Inc. for analysis.  These were identified as counterfeit by the manufacturer that also examined some of the counterfeit capacitors.

Fig. A – Rubber seal styles for capacitor samples

There were a variety of construction anomalies associated with these samples. These are listed below by sample. 

Sample A – Poorly constructed roll where lead spacing appeared to be bad and close proximity of swage to end of anode foil extremely unusual, as well as proximity of anode & cathode terminations. 5-swage terminations. 

Sample B – same as A (except 3-swage terminations) 

Sample C – 4-swage terminations, position of lead attachment on roll more typical than A or B where attachment was near start of roll. Corrosion damage in beginning stage on anode lead. Seal appears poor and damaged by stave on lead. 

Sample D – 5-swage terminations, position of lead attachment on roll more typical than A or B where attachment was near start of roll. Corrosion damage in beginning stage on anode lead. Seal appears poor and damaged by stave on lead. D foil appears different than C foil.

Fig. B – Sample A – failed capacitor #1. This is the EDS spectrum of corrosion product on the anode near the corroded termination.

The analysis results suggest that the two failed samples became open-circuited due to internal corrosion at the anode lead. These failures may have been accelerated by poor quality seals and construction features that permitted ingress of external contamination (e.g. Cl) and moisture. The not-yet-failed samples also showed initial stages of corrosion failure at the anode lead/seal. 

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A client provided a failed metal thin film resistor (Nichrome) to SEM Lab for failure analysis. 

The analysis results suggest that the resistor failed due to corrosion of the edge of the NiCr resistor pattern.  The removal of material by the corrosion process created an open (likely multiple opens) in the resistor pattern.

A client provided several resistors to SEM Lab, Inc. for SEM/EDS analysis. The client reported seeing “yellowing” of the metallization after solder reflow on some components, most notably 0603 resistors. We examined both discolored (post reflow) and stock parts (control).
 

 Sungil Cho et al [1] studied oxidation kinetics for lead-free alloys and reported that silver modifies the oxidation rate of tin (i.e. promote the formation of tin oxides). It seems likely that the yellowing is related to thick oxide formation due to combination of factors including (1) excessive time-temperature exposure (2) silver availability from the silver-thick-film in the resistor and/or the silver in the SAC alloy.
 

Resistor manufacturers offer designs that are improved with respect to exposure of the silver-thick-film in the resistor to corrosion (usually by sulfur), e.g. Thick Film Chip Resistors, Military/Established Reliability MIL-PRF-55342 Qualified, Type RM. It was suggested that the client obtain some of the Type RM resistors and determine if they are also more immune to yellowing during reflow on this assembly.
 

[1] Sungil Cho et al, “The Oxidation of Lead-Free Sn Alloys by Electrochemical Reduction Analysis”, Journal of Metals, June 2005, pp. 50 – 52.
 

Check out SEM Lab, Inc.  to learn more.

A client provided some sample PCBs (1 bare, 1 assembled) that were exhibiting discoloration on the ENIG plated surface. The client asked us to characterize this defect and determine root cause.

The nickel (EN) deposit appears normal except at the interface with the gold (IG layer).  The defects (shown by the yellow arrows) are referred to as “IG spiking”, where the gold plating solution etches the Ni-P grain boundaries.  This creates small voids or pits under the IG plating that trap process chemistry and cause corrosion resulting in the stain on the surface.  Root cause = IG spiking.  A secondary cause is water droplets left on the board surface after cleaning.

Check out SEM Lab, Inc.  to learn more.